Mononuclear, Nonheme, High-Spin {FeNO}7/8 Complexes Supported by a Sterically Encumbered N4S-Thioether Ligand
نویسندگان
چکیده
منابع مشابه
Mononuclear three-coordinate magnesium complexes of a highly sterically encumbered β-diketiminate ligand.
The highly sterically encumbered chelating β-diketiminate ligand, [HC{C(Me)N(2,6-CHPh2-4-MeC6H2)}2](-), (Ar)L(-), has been used to prepare a series of heteroleptic three-coordinate magnesium complexes. Both the bis(imine) and imine-enamine tautomers of the ligand precursor, (Ar)LH, as well as the diethyl ether adduct of the bromide complex [(Ar)LMgBr(OEt2)], the monomeric methyl complex [(Ar)LM...
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Mononuclear nonheme high-spin iron(III)-acylperoxo complexes bearing an N-methylated cyclam ligand were synthesized, spectroscopically characterized, and investigated in olefin epoxidation and alkane hydroxylation reactions. In the epoxidation of olefins, epoxides were yielded as the major products with high stereo-, chemo-, and enantioselectivities; cis- and trans-stilbenes were oxidized to ci...
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Stable and active Ru olefin metathesis catalyst 7 bearing a sterically reduced NHC ligand was synthesized. Upon action of pyridine, 7 forms complex 24, the first example of an Ru–indenylidene catalyst bearing a labile pyridine ligand and a sterically less demanding NHC ligand.
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The synthesis, structure, and spectroscopic signatures of a series of four-coordinate iron(II) complexes of β-ketoiminates and their zinc(II) analogues are presented. An unusual five-coordinate iron(II) triflate with three oxygen bound protonated β-ketoimines is also synthesized and structurally characterized. Single-crystal X-ray crystallographic analysis reveals that the deprotonated bis(chel...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2019
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.9b01475